2,3-二甲基-2-丁醇

2,3-二甲基-2-丁醇
英文名
识别
CAS号	594-60-5
性质
化学式	C6H14O
摩尔质量	102.17 g·mol−1
密度	0.8294 g·cm−3（20 °C）[1]; 0.8155 g·cm−3（25 °C）[2]
熔点	−11.3 °C（261.8 K）[3]; −14 °C（259 K）[4]
沸点	118.4 °C（391.5 K）[4]; 118.6 °C（391.8 K）[5]
溶解性（水）	2.3 g（25 °C）[6]
pKa	15.24±0.29[6]
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

2,3-二甲基-2-丁醇是一种有机化合物，化学式为C₆H₁₄O是六碳醇的同分异构体之一。它可由2,3-二甲基-2-丁烯的硼氢化-氧化反应制得。[7]甲基(三氟甲基)过氧化酮对2,3-二甲基丁烷的氧化也能得到该产物。[8]它和金属的二(三甲基硅基)氨基化物反应，生成金属的醇盐。[9]

参考文献

Levina, R. Ya.; Tantsyreva, T. I.; Fainzil'berg, A. A. Synthesis of hydrocarbons. XX. Synthesis of alkenes and alkanes with a quaternary carbon atom. Zhurnal Obshchei Khimii, 1952. 22: 571-577. ISSN: 0044-460X.
C. G. Overberger, M. B. Berenbaum. . Journal of the American Chemical Society. 1952-07, 74 (13): 3293–3295 [2019-11-08]. ISSN 0002-7863. doi:10.1021/ja01133a022 （英语）.
M. GaŁązka, E. Juszyńska, P.M. Zieliński. . Physica B: Condensed Matter. 2011-12, 406 (23): 4342–4349 [2019-11-08]. doi:10.1016/j.physb.2011.08.065. （原始内容存档于2018-06-09）（英语）.
"PhysProp" data were obtained from Syracuse Research Corporation of Syracuse, New York (US). Retrieved from SciFinder. [2019-11-8]
Mohammad Goodarzi, Matheus P. Freitas. . The Journal of Physical Chemistry A. 2008-11-06, 112 (44): 11263–11265 [2019-11-08]. ISSN 1089-5639. doi:10.1021/jp8059085 （英语）.
Calculated using Advanced Chemistry Development (ACD/Labs) Software V11.02 (© 1994-2019 ACD/Labs). Retrieved from SciFinder. [2019-11-8]
Herbert C. Brown, M. Mark Midland, George W. Kabalka. . Tetrahedron. 1986-01, 42 (20): 5523–5530 [2019-11-08]. doi:10.1016/S0040-4020(01)88155-2 （英语）.
Jack K. Crandall, Ruggero Curci, Lucia D'Accolti, Caterina Fusco. . John Wiley & Sons, Ltd. 2005-10-15 [2019-11-08]. ISBN 9780471936237. doi:10.1002/047084289x.rm267.pub2 （英语）.
Timo Hatanpää, Kaupo Kukli, Mikko Ritala, Markku Leskelä. . Journal of Thermal Analysis and Calorimetry. 2011-07, 105 (1): 61–71 [2019-11-08]. ISSN 1388-6150. doi:10.1007/s10973-011-1546-1 （英语）.

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[1] Levina, R. Ya.; Tantsyreva, T. I.; Fainzil'berg, A. A. Synthesis of hydrocarbons. XX. Synthesis of alkenes and alkanes with a quaternary carbon atom. Zhurnal Obshchei Khimii, 1952. 22: 571-577. ISSN: 0044-460X.

[2] C. G. Overberger, M. B. Berenbaum. . Journal of the American Chemical Society. 1952-07, 74 (13): 3293–3295 [2019-11-08]. ISSN 0002-7863. doi:10.1021/ja01133a022 （英语）.

[3] M. GaŁązka, E. Juszyńska, P.M. Zieliński. . Physica B: Condensed Matter. 2011-12, 406 (23): 4342–4349 [2019-11-08]. doi:10.1016/j.physb.2011.08.065. （原始内容存档于2018-06-09）（英语）.

[Phys-4] "PhysProp" data were obtained from Syracuse Research Corporation of Syracuse, New York (US). Retrieved from SciFinder. [2019-11-8]

[5] Mohammad Goodarzi, Matheus P. Freitas. . The Journal of Physical Chemistry A. 2008-11-06, 112 (44): 11263–11265 [2019-11-08]. ISSN 1089-5639. doi:10.1021/jp8059085 （英语）.

[ACD-6] Calculated using Advanced Chemistry Development (ACD/Labs) Software V11.02 (© 1994-2019 ACD/Labs). Retrieved from SciFinder. [2019-11-8]

[7] Herbert C. Brown, M. Mark Midland, George W. Kabalka. . Tetrahedron. 1986-01, 42 (20): 5523–5530 [2019-11-08]. doi:10.1016/S0040-4020(01)88155-2 （英语）.

[8] Jack K. Crandall, Ruggero Curci, Lucia D'Accolti, Caterina Fusco. . John Wiley & Sons, Ltd. 2005-10-15 [2019-11-08]. ISBN 9780471936237. doi:10.1002/047084289x.rm267.pub2 （英语）.

[9] Timo Hatanpää, Kaupo Kukli, Mikko Ritala, Markku Leskelä. . Journal of Thermal Analysis and Calorimetry. 2011-07, 105 (1): 61–71 [2019-11-08]. ISSN 1388-6150. doi:10.1007/s10973-011-1546-1 （英语）.