4-溴溴苄

4-溴溴苄是一种有机化合物,化学式为C7H6Br2。它可由4-溴甲苯N-溴代丁二酰亚胺偶氮二异丁腈过氧化苯甲酰存在下于四氯化碳碳酸二乙酯中反应制得;[3][4]4-溴苯甲醇和三溴化磷反应也能得到4-溴溴苄。[5]它在铜修饰二氧化钛光催化剂的催化下可以发生C-C偶联反应,生成1,2-二(4-溴苯基)乙烷。[6]它和叠氮化钠反应,得到4-叠氮甲基溴苯。[7]它和硫代硫酸钠反应,得到4-溴苄基硫代硫酸钠。[8]

4-溴溴苄
别名 对溴溴苄
4-溴甲基溴苯
α,p-二溴甲苯
识别
CAS号 589-15-1  checkY
性质
化学式 C7H6Br2
摩尔质量 249.93 g·mol−1
熔点 63 °C(336 K)[1]
沸点 115—124 °C(388—397 K)(12 mmHg)[2]
相关物质
相关化学品 1,4-二溴苯
1,4-二(溴甲基)苯
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

参考文献

  1. "PhysProp" data were obtained from Syracuse Research Corporation of Syracuse, New York (US). Retrieved from SciFinder. [2021-07-06].
  2. Goerner, Gordon L.; Nametz, Richard C. . Journal of the American Chemical Society. 2002, 73 (6): 2940–2941. ISSN 0002-7863. doi:10.1021/ja01150a509.
  3. Yan Zhong, Yi Xu, Ai-Xia Zhang, Xiao-Feng Li, Zhao-Ying Xu, Ping Li, Bin Wu. . Bioorganic & Medicinal Chemistry Letters. 2016-05, 26 (10): 2526–2530 [2021-07-06]. doi:10.1016/j.bmcl.2016.03.094. (原始内容存档于2018-06-29) (英语).
  4. Subramanya R. K. Pingali, Sunil K. Upadhyay, Branko S Jursic. . Green Chemistry. 2011, 13 (4): 928 [2021-07-06]. ISSN 1463-9262. doi:10.1039/c0gc00794c (英语).
  5. Rajendiran Balasaravanan, Kumaraguru Duraimurugan, Jayaraman Sivamani, Viruthachalam Thiagarajan, Ayyanar Siva. . New Journal of Chemistry. 2015, 39 (9): 7472–7480 [2021-07-06]. ISSN 1144-0546. doi:10.1039/C5NJ00605H (英语).
  6. Li, Yaru; Ren, Pengju; Zhang, Dongsheng; Qiao, Wei; Wang, Dan; Yang, Xiaoqin; Wen, Xiaodong; Rummeli, Mark H.; Niemantsverdriet, Hans; Lewis, James P.; Besenbacher, Flemming; Xiang, Hongwei; Li, Yongwang; Su, Ren. . ACS Catalysis. 2021, 11 (7): 4338–4348. ISSN 2155-5435. doi:10.1021/acscatal.1c00102.
  7. Cutler, Alan; Ralph, Greg L.; Zuma, Nonkululeko H.; Aucamp, Janine; N’Da, David D. . Arkivoc. 2020, 2020 (5): 39–58. ISSN 1551-7012. doi:10.24820/ark.5550190.p011.312.
  8. Muhannad A. E. Al-Saedy, Joseph P. A. Harrity. . Synlett. 2020-07, 31 (12): 1182–1184 [2021-07-06]. ISSN 0936-5214. doi:10.1055/s-0040-1707108 (英语).
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