1-十九烷醇

1-十九烷醇是一种有机化合物,化学式为C19H40O,可由十九酸的还原反应制得。[3]它和三苯基膦催化下反应[4],或和四溴化碳、三苯基膦在二氯甲烷中反应[5],可以得到1-溴十九烷。它和对甲苯磺酰氯反应,生成相应的[6]

1-十九烷醇
Structural model of 1-nonadecanol
IUPAC名
nonadecan-1-ol
别名 1-十九醇
正十九醇
识别
CAS号 1454-84-8  checkY
PubChem 80281
ChemSpider 72522
SMILES
 
  • CCCCCCCCCCCCCCCCCCCO
性质
化学式 C19H40O
摩尔质量 284.52 g·mol−1
熔点 59—61 °C(332—334 K)[1]
62—63 °C(335—336 K)[2]
沸点 204—217 °C(477—490 K)(3 torr)[1]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

参考文献

  1. James Cason, Helen J. Wolfhagen, Winifred Tarpey, Raylene E. Adams. . The Journal of Organic Chemistry. 1949-01, 14 (1): 147–154 [2021-03-17]. ISSN 0022-3263. doi:10.1021/jo01153a021 (英语).
  2. Scholl, A. W.; Morrison, J. G. Preparation and properties of n-nonadecyl and n-eicosyl formates. West Va. Univ. Bull., Proc. West Va. Acad. Sci., 1955. V1954. 26: 35-37. CAN50: 44260.
  3. Juma'a R. Al Dulayymi, Mark S. Baird, Evan Roberts. . Tetrahedron. 2005-12, 61 (50): 11939–11951 [2021-03-17]. doi:10.1016/j.tet.2005.09.056. (原始内容存档于2018-07-02) (英语).
  4. Oldřich Kocián, Karel Stránský, Jiří Závada. . Collection of Czechoslovak Chemical Communications. 1982, 47 (5): 1346–1355 [2021-03-17]. ISSN 0010-0765. doi:10.1135/cccc19821346. (原始内容存档于2018-06-05) (英语).
  5. Yasuhisa Yamamura, Yuri Nakazawa, Shoichi Kutsumizu, Kazuya Saito. . Physical Chemistry Chemical Physics. 2019, 21 (42): 23705–23712 [2021-03-17]. ISSN 1463-9076. doi:10.1039/C9CP04424H (英语).
  6. Kaoru Marukawa, Hirosato Takikawa, Kenji Mori. . Bioscience, Biotechnology, and Biochemistry. 2001-01, 65 (2): 305–314 [2021-03-17]. ISSN 0916-8451. doi:10.1271/bbb.65.305. (原始内容存档于2022-01-21) (英语).
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