1,2-己二醇

1,2-己二醇是一种有机化合物,结构上属于邻二醇,其化学式为C6H14O2。它可由1-己烯高碘酸钠-氯化钌氧化得到。[2]它在氧化铝负载的氟化铯催化下和碳酸二乙酯反应,可以得到碳酸-1,2-己烯酯。[3]它在二氯甲烷中被硅胶负载的高锰酸钾氧化,可以得到戊酸[4]

1,2-己二醇
识别
CAS号 6920-22-5  checkY
SMILES
 
  • OCC(O)CCCC
性质
化学式 C6H14O2
摩尔质量 118.17 g·mol−1
沸点 112-113 °C(12 mmHg)[1]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

参考文献

  1. Ammonolysis of Vicinal Acetoxy Chlorides. J. Org. Chem., 1961. 26. doi:10.1021/jo01068a015.
  2. Enhancing selectivity in oxidation catalysis with sol–gel nanocomposites. Org. Biomol. Chem., 2005, 3, 2389-2392. doi:10.1039/B505949F.
  3. Correlation between the basicity of solid bases and their catalytic activity towards the synthesis of unsymmetrical organic carbonates. Journal of Catalysis, 2005. 229 (1): 237-242. doi:10.1016/j.jcat.2004.10.024.
  4. Oxidative studies of vicinal diols, α-hydroxy ketones and α-diketones using solid-supported potassium permanganate on silica gel. Journal of the Brazilian Chemical, 1994. 5 (2): 67-68. doi:10.5935/0103-5053.19940011.
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