笼效应
举例
- 在凝聚态相或稠密气体中,反应物分子聚在一起,它们被周围分子包围,受到许多碰撞
- 分子解离,不能很快离开,因为有其它分子阻挡,结果,解离可发生重组合
- 在溶剂笼内的分子,偶然跳出笼,并遇上另一分子而发生反应
参考文献
- PAC, 1996,68. 149(A glossary of terms used in chemical kinetics, including reaction dynamics)(IUPAC Recommendation 1996) on Page 155
This article is issued from Wikipedia. The text is licensed under Creative Commons - Attribution - Sharealike. Additional terms may apply for the media files.