甲酸镍

甲酸镍是镍和甲酸形成的盐,化学式为Ni(HCOO)2。它可由甲酸钠硫酸镍在热水中反应,冷却后析出得到。[1]它热分解生成金属[2]它除了可以形成水合物外,还可以和吡啶形成配合物。[3]

甲酸镍

识别
CAS号 3349-06-2(无水)  checkY
15694-70-9(二水)  checkY
性质
化学式 C2H2NiO4
摩尔质量 148.73 g·mol−1
溶解性 0.15 mol/L(二水,25 °C)
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

参考文献

  1. Kaminskii, N. A. Production of nickel formate. Masloboino-Zhirovaya Promyshlennost, 1954. 19 (4): 31-32. ISSN 0368-8712.
  2. Anna N. Puzan, Vyacheslav N. Baumer, Dmytro V. Lisovytskiy, Pavel V. Mateychenko. . Journal of Solid State Chemistry. 2018-10, 266: 133–142 [2022-03-23]. doi:10.1016/j.jssc.2018.07.005. (原始内容存档于2020-02-18) (英语).
  3. Arnaiz Garcia, F. J.; Perez Manrique, M. M. Study of nickel formate and its addition products with ammonia, pyridine, and 4-methylpyridine. Ion (Madrid), 1976. 36 (420): 422-425. ISSN 0375-9091.
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