四氢金雀花碱

四氢金雀花碱是一种有机化合物,化学式为C11H18N2O,可由金雀花碱二氧化铂催化下氢化得到。[1]它在四氢呋喃中可以被氢化铝锂还原为脱氧四氢金雀花碱。[2]它和苄溴碳酸钾存在下于丙酮中反应,可以得到3-苄基四氢金雀花碱。[3]

四氢金雀花碱
识别
CAS号 18161-94-9  checkY
PubChem 519524
SMILES
 
  • O=C1N2[C@]([C@@]3(C[C@](C2)(CN(CC)C3)[H])[H])(CCC1)[H]
性质
化学式 C11H18N2O
摩尔质量 194.27 g·mol−1
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

参考文献

  1. Sandulenko, Yu. B.; Ivashchenko, A. V.; Kravchenko, D. V.; Tkachenko, S. E.; Vvedensky, V. Yu. Russian Chemical Bulletin (2008), 57(9), 1999-2004. doi:10.1007/s11172-008-0269-3.
  2. Philipova, Irena; Stavrakov, Georgi; Vassilev, Nikolay; Nikolova, Rositsa; Shivachev, Boris; Dimitrov, Vladimir Journal of Organometallic Chemistry (2015), 778, 10-20. doi:10.1016/j.jorganchem.2014.12.001
  3. Alexander V. Ivachtchenko, Sergey E. Tkachenko, Yuriy B. Sandulenko, Vladimir Y. Vvedensky, and Alexander V. Khvat. J. Comb. Chem. 2004, 6, 5, 828–834. doi:10.1021/cc0499385.
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