人参三醇

人参三醇Panaxatriol)是一种甾体化合物,分子式C
30
H
52
O
4
,具有达玛烷骨架。气相色谱法分析人参总皂苷含量时,使用丁醇碱溶液水解人参皂苷,人参皂苷的水解产物之一为原人参三醇。人参三醇是前者羟基和烯键环合得到的同分异构体,同时也是标准加入法定量分析人参皂苷的标准物质[1]

人参三醇
IUPAC名
(3S,5R,6R,8R,9R,10R,12R,13R,14R,17S)-4,4,8,10,14-pentamethyl-17-[(2R)-2,6,6-trimethyloxan-2-yl]-2,3,5,6,7,9,11,12,13,15,16,17-dodecahydro-1H-cyclopenta[a]phenanthrene-3,6,12-triol
系统名
(1R,2R,5S,7R,8R,10R,11R,14S,15R,16R)-2,6,6,10,11-pentamethyl-14-[(1R)-1,3,3-trimethyl-2-oxacyclohexyl]tetracyclo[8.7.0.02,7.011,15]heptadecane-5,8,16-triol

(1R,2R,5S,7R,8R,10R,11R,14S,15R,16R)-2,6,6,10,11-五甲基-14-[(1R)-1,3,3-三甲基-2-氧杂环己基]四环[8.7.0.02,7.011,15]-5,8,16-十七烷三醇

别名 (20R)-20,25-Epoxydammarane-3β,6β,12β-triol
识别
CAS号 32791-84-7  checkY
PubChem 73599
ChemSpider 66270
SMILES
 
  • C[C@@]1(CCCC(O1)(C)C)[C@H]2CC[C@@]3([C@@H]2[C@@H](C[C@H]4[C@]3(C[C@H]([C@@H]5[C@@]4(CC[C@@H](C5(C)C)O)C)O)C)O)C
InChI
 
  • 1/C30H52O4/c1-25(2)12-9-13-30(8,34-25)18-10-15-28(6)23(18)19(31)16-21-27(5)14-11-22(33)26(3,4)24(27)20(32)17-29(21,28)7/h18-24,31-33H,9-17H2,1-8H3/t18-,19+,20+,21+,22-,23-,24-,27+,28+,29+,30+/m0/s1
InChIKey QFJUYMMIBFBOJY-UXZRXANABD
性质
化学式 C30H52O4
476.73 g/mol g·mol¹
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

参考资料

  1. Cui, Jian-fang. . European journal of pharmaceutical sciences. 1995, 3 (2): 77-85.
This article is issued from Wikipedia. The text is licensed under Creative Commons - Attribution - Sharealike. Additional terms may apply for the media files.